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Recovery of ferric chloride. HAM Tips

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During the etching of printed circuit boards, the ferric chloride solution gradually loses its activity, and the etching rate decreases. This is due to the fact that the solution is saturated with copper ions.

Usually such a solution is drained. However, its activity can be restored in a simple way. You can immerse several large steel nails in the spent solution. After some time, excess copper from the solution will settle on the surface of the nails and on the bottom of the vessel. After that, the solution is poured into another vessel, the copper is removed from the pickling bath, the nails are cleaned, and then they are put back into the bath and filled with the same solution. As copper accumulates on nails, it is removed.

Thus, it is possible to significantly extend the "life" of the ferric chloride solution.

Author: V. Kolobov

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Comments on the article:

Jury
I personally checked it several times: ferric chloride becomes completely unusable after such a restoration. [:(]

Mitiai
Often attempts are made to "regenerate" the FeCl3 solution by throwing iron scrap, shavings, etc. into it, supposedly to displace the dissolved copper. After etching, FeCl3, FeCl2, and CuCl2 remain in the solution. Although FeCl2 is not very stable in air, some equilibrium is nevertheless established with CuCl2 (but after a while it will still be oxidized by atmospheric oxygen). By adding iron, we displace copper from the solution, in which only iron chlorides II and III remain. In turn, FeCl2 is very quickly oxidized by atmospheric oxygen, but not to FeCl3, but to basic iron salts that precipitate. And then the scrap iron begins to interact with iron chloride III, also rendering it unusable. FeCl3 + Fe ==> FeCl2 FeCl2 + H2O + O2 ==> Fe(Cl)x(OH)y It can be regenerated by electrolysis, at low current, then copper will be released on the graphite cathode, and chlorine will have time to dissolve. But this process is very slow. An attempt to intensify it by raising the current will lead to the release of unreacted chlorine gas. Chlorine is poisonous. So making a new solution will be easier.


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