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Section 7. Electrical equipment of special installations
Electrical installations in hazardous areas. Classification of explosive mixtures according to GOST 12.1.011-78
Encyclopedia of radio electronics and electrical engineering / Rules for the installation of electrical installations (PUE)
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7.3.26. Explosive mixtures of gases and vapors with air, depending on the size of the BEMZ, are divided into categories according to Table. 7.3.1.
7.3.27. Explosive mixtures of gases and vapors with air, depending on the temperature of self-ignition, are divided into six groups according to Table. 7.3.2.
7.3.28. The distribution of explosive mixtures of gases and vapors with air by categories and groups is given in Table. 7.3.3.
Table 7.3.1. Categories of explosive mixtures of gases and vapors with air *
Blend category |
Mixture name |
BEMZ, mm |
I |
mine methane |
More 1,0 |
II |
Industrial gases and vapors |
- |
IIA |
Also |
More 0,9 |
IIB |
Also |
More than 0,5 to 0,9 |
IIC |
Also |
Until 0,5 |
* The BEMZ values given in the table cannot be used to control the shell gap width in operation.
Table 7.3.2. Groups of explosive mixtures of gases and vapors with air by auto-ignition temperature
Group |
Self-ignition temperature of the mixture, ºС |
Group |
Self-ignition temperature of the mixture, ºС |
T1 |
above 450 |
T4 |
Above 135 to 200 |
T2 |
"300 to 450 |
T5 |
"100 to 135 |
TK |
"200 to 300 |
T6 |
"85 to 100 |
Table 7.3.3. Distribution of explosive mixtures by categories and groups
Blend category |
Mix group |
Substances that form an explosive mixture with air |
I |
T1 |
Methane (mine)* |
iia |
T1 |
Ammonia, allyl chloride, acetone, acetonitrile, benzene, benzotrifluoride, vinyl chloride, vinylidene chloride, 1,2-dichloropropane, dichloroethane, diethylamine, diisopropyl ether, blast furnace gas, isobutylene, isobutane, isopropylbenzene, acetic acid, xylene, methane (industrial)**, methyl acetate, α-methylstyrene, methyl chloride, methyl isocyanate, methyl chloroformate, methylcyclopropyl ketone, methyl ethyl ketone, carbon monoxide, propane, pyridine, solvents R-4, R-5 and RS-1, diluent RE-1, petroleum solvent, styrene, diacetone alcohol, toluene, trifluorochloropropane, trifluoropropene, trifluoroethane, trifluorochlorethylene, triethylamine, chlorobenzene, cyclopentadiene, ethane, ethyl chloride |
T2 |
Alkylbenzene, amyl acetate, acetic anhydride, acetylacetone, acetyl chloride, acetopropyl chloride, gasoline B95/130, butane, butyl acetate, butyl propionate, vinyl acetate, vinylidene fluoride, diatol, diisopropylamine, dimethylamine, dimethylformamide, isopentane, isoprene, isopropylamine, isooctane, propionic acid, methylamine , methylisobutyl ketone, methyl methacrylate, methyl mercaptan, methyltrichlorosilane, 2-methylthiophene, methylfuran, monoisobutylamine, methylchloromethyldichlorosilane, mesityl oxide, pentadiene-1,3, propylamine, propylene. Solvents: No. 646, 647, 648, 649, RS-2, BEF and AE. Thinners: RDV, RKB-1, RKB-2. Alcohols: butyl normal, butyl tertiary, isoamyl, isobutyl, isopropyl, methyl, ethyl. Trifluoropropylmethyldichlorosilane, trifluoroethylene, trichlorethylene, isobutyl chloride, ethylamine, ethyl acetate, ethylbutyrate, ethylenediamine, ethylenechlorohydrin, ethylisobutyrate, ethylbenzene, cyclohexanol, cyclohexanone |
IIA |
T3 |
Gasolines: A-66, A-72, A-76, “galosh”, B-70, extraction according to TU 38.101.303-72, extraction according to MRTU12N-20-63. Butyl methacrylate, hexane, heptane, diisobutylamine, dipropylamine, isovaleric aldehyde, isooctylene, camphene, kerosene, morpholine, petroleum, petroleum ether, TGM-3 polyester, pentane, solvent No. 651, turpentine, amyl alcohol, trimethylamine, T-1 and TS fuel -1, white spirit, cyclohexane, cyclohexylamine, ethyl dichlorothiophosphate, ethyl mercaptan |
IIA |
T4 |
Acetaldehyde, isobutyric aldehyde, butyric aldehyde, propionic aldehyde, decane, tetramethyldiaminomethane, 1,1,3-triethoxybutane |
T5 |
- |
T6 |
- |
IIB |
T1 |
coke oven gas, hydrocyanic acid |
T2 |
Divinyl, 4,4-dimethyldioxane, dimethyldichlorosilane, dioxane, diethyldichlorosilane, camphor oil, acrylic acid, methyl acrylate, methylvinyldichlorosilane, acrylic acid nitrile, nitrocyclohexane, propylene oxide, 2-methylbutene-2 oxide, ethylene oxide, AMP-3 and AKP solvents , trimethylchlorosilane, formaldehyde, furan, furfural, epichlorohydrin, ethyltrichlorosilane, ethylene |
IIB |
T3 |
Acrolein, vinyl trichlorosilane, hydrogen sulfide, tetrahydrofuran, tetraethoxylan, triethoxysilane, diesel fuel, formal glycol, ethyl dichlorosilane, ethyl cellosolve |
T4 |
Dibutyl Ether, Diethyl Ether, Ethylene Glycol Diethyl Ether |
T5 |
- |
T6 |
- |
IIC |
T1 |
Hydrogen, water gas, light gas, hydrogen 75% + nitrogen 25% |
T2 |
Acetylene, methyldichlorosilane |
T3 |
Trichlorosilane |
T4 |
- |
T5 |
carbon disulfide |
T6 |
- |
* Mine methane should be understood as mine gas, in which, in addition to methane, the content of gaseous hydrocarbons - homologues of C2-C5 methane - is no more than 0,1 volume fraction, and hydrogen in gas samples from boreholes immediately after drilling is no more than 0,002 volume fraction of the total volume of combustible gases .
** In industrial methane, the hydrogen content can be up to 0,15 volume fraction.
7.3.29. The lower concentration limit of ignition of some explosive dusts, as well as their smoldering, ignition and self-ignition temperatures are given in Table. 7.3.4.
7.3.30. Categories and groups of explosive mixtures of gases and vapors with air, as well as smoldering, ignition and self-ignition temperatures of dust not included in the table. 7.3.3 and 7.3.4 are determined by testing organizations in accordance with their list in accordance with GOST 12.2.021-76.
Table 7.3.4. The lower concentration limit of ignition, the temperature of smoldering, ignition and self-ignition of explosive dusts
Substance |
suspended dust |
Settled dust |
Lower concentration limit of ignition, g/m3 |
Ignition temperature, ºС |
Smoldering temperature, ºС |
Ignition temperature, ºС |
Self-ignition temperature, ºС |
adipic acid |
35 |
550 |
- |
320 |
410 |
Altax |
37,8 |
645 |
Does not smolder, melts at 186 ºС |
- |
- |
Aluminum |
40 |
550 |
320 |
- |
470 |
Aminopelargonic acid |
10 |
810 |
Does not smolder, melts at 190 ºС |
- |
- |
Aminoplast |
52 |
725 |
264 |
- |
559 |
Aminoenanthic acid |
12 |
740 |
Does not smolder, melts at 195 ºС |
390 |
450* |
4-Amilbenzophenone 2-carboxylic acid |
23,4 |
562 |
Does not smolder, melts at 130 ºС |
261 |
422* |
Ammonium salt of 2,4-dioxybenzene-sulfonic acid |
63,6 |
- |
Does not smolder, melts |
286 |
470 |
Anthracene |
5 |
505 |
Does not smolder, melts at 217 ºС |
- |
- |
Atrazine technical, TU BU-127-69 |
30,4 |
779 |
Does not smolder, melts at 170 ºС |
220 |
490* |
Atrazine commercial |
39 |
745 |
Also |
228 |
487* |
Sunflower food protein |
26,3 |
- |
193 |
212 |
458 |
soy protein food |
39,3 |
- |
Does not smolder, charred |
324 |
460 |
Bis(trifluoroacetate)dibutyltin |
21,2 |
554 |
Does not smolder, melts at 50 ºС |
158 |
577* |
Vitamin B15 |
28,2 |
509 |
- |
- |
- |
Vitamin PP from rose hips |
38 |
610 |
- |
- |
- |
Hydroquinone |
7,6 |
800 |
- |
- |
- |
Pea flour |
25 |
560 |
- |
- |
- |
Dextrin |
37,8 |
400 |
- |
- |
- |
Dicyclopentadiene dioxide, TU 6-05-241-49-73 |
19 |
- |
Does not smolder |
129 |
394 |
2,5-Dimethylhexin-3-diol-2,5 |
9,7 |
- |
Does not smolder, melts at 90ºС |
121 |
386* |
wood flour |
11,2 |
430 |
- |
- |
255 |
casein |
45 |
520 |
- |
- |
- |
Cocoa |
45 |
420 |
245 |
- |
- |
Camphor |
10,1 |
850 |
- |
- |
- |
Rosin |
12,6 |
325 |
Does not smolder, melts at 80ºС |
- |
- |
Kerogen |
25 |
597 |
- |
- |
- |
Potato starch |
40,3 |
430 |
Does not smolder, charred |
- |
- |
Corn starch |
32,5 |
410 |
Does not smolder, charred |
- |
- |
hardwood lignin |
30,2 |
775 |
- |
- |
300 |
Cotton lignin |
63 |
775 |
- |
- |
- |
Softwood lignin |
35 |
775 |
- |
- |
300 |
Dibutyltin maleate |
23 |
649 |
- |
220 |
458* |
Maleic anhydride |
50 |
500 |
Does not smolder, melts at 53º C |
- |
- |
Methyltetrahydrophthalic anhydride |
16,3 |
488 |
Does not smolder, melts at 64ºС |
155 |
482* |
Microvit A feed, TU 64-5-116-74 |
16,1 |
- |
Does not smolder, charred |
275 |
463 |
Flour dust (wheat, rye and other grain crops) |
20-63 |
410 |
- |
- |
205 |
Naphthalene |
2,5 |
575 |
Does not smolder, melts at 80ºС |
- |
- |
Dibutyltin oxide |
22,4 |
752 |
154 |
154 |
523 |
Dioctyltin oxide |
22,1 |
454 |
Does not smolder, melts at 155 ºС |
155 |
448* |
Polyacrylonitrile |
21,2 |
505 |
Does not smolder, charred |
217 |
- |
Polyvinyl alcohol |
42,8 |
450 |
Does not smolder, melts at 180-220 ºС |
205 |
344* |
Polyisobutylaluminumoxane |
34,5 |
- |
Does not smolder |
76 |
514 |
Polypropylene |
12,6 |
890 |
- |
- |
- |
Polysebacin anhydride (hardener VII-607), MRTU 6-09-6102-69 |
19,7 |
538 |
Does not smolder, melts at 80 ºС |
266 |
381* |
Polystyrene |
25 |
475 |
Does not smolder, melts at 220ºС |
- |
- |
Powder paint P-EP-177, item 518 VTU 3609-70, with additive No. 1, gray color |
16,9 |
560 |
Does not smolder |
308 |
475 |
Powder paint P-EP-967, item 884, VTU 3606-70, red-brown color |
37,1 |
848 |
Also |
308 |
538 |
Powder paint EP-49-D/2, VTU 605-1420-71, brown |
33,6 |
782 |
Also |
318 |
508 |
Powder paint PVL-212, MPTU 6-10-859-69, ivory |
25,5 |
580 |
- |
241 |
325 |
Powder paint P-EP-1130U, VTU NC No. 6-37-72 |
33,5 |
633 |
Also |
314 |
395 |
Propazine technical |
27,8 |
775 |
Does not smolder, melts at 200 ºС |
226 |
435* |
Commercial propazine, TU 6-01-171-67 |
37,2 |
763 |
Does not smolder, melts at 200 ºС |
215 |
508* |
cork flour |
15 |
460 |
325 |
- |
- |
Dust of Leninsk-Kuznetsk hard coal grade D, Yaroslavsky mine |
31 |
720 |
149 |
159 |
480 |
Industrial rubber dust |
10,1 |
1000 |
- |
- |
200 |
Dust industrial cellolignin |
27,7 |
770 |
- |
- |
350 |
Shale dust |
58 |
830 |
- |
|
225 |
Sucap (acrylic acid polymer TU 6-02-2-406-75) |
47,7 |
- |
Does not smolder |
292 |
448 |
Beet sugar |
8,9 |
360 |
Does not smolder, melts at 160 ºС |
- |
350* |
Sulfur |
2,3 |
235 |
Does not smolder, melts at 119 ºС |
- |
- |
Simazin technical, TU BU-104-68 |
38,2 |
790 |
Does not smolder, melts at 220 ºС |
224 |
472* |
Simazin commodity, MRTU 6-01-419-69 |
42,9 |
740 |
Does not smolder, melts at 225 ºС |
265 |
476* |
Resin 113-61 (dioctyltin thioestanate) |
12 |
- |
Does not smolder, melts at 68 ºС |
261 |
389* |
Salt AG |
12,6 |
636 |
- |
- |
- |
Copolymer of acrylonitrile with methyl methacrylate |
18,8 |
532 |
Does not smolder, charred |
274 |
- |
Stabilizer 212-05 |
11,1 |
- |
Does not smolder, melts at 57 ºС |
207 |
362* |
Glass organic |
12,6 |
579 |
Does not smolder, melts at 125 ºС |
- |
300* |
Sulfadimezin |
25 |
900 |
- |
- |
- |
Titanium |
45 |
330 |
- |
- |
- |
Thiooxyethylene dibutyltin |
13 |
214 |
Does not smolder, melts at 90 ºС |
200 |
228* |
Triphenyltrimethylcyclotrisiloxane |
23,4 |
515 |
Does not smolder, melts at 60 ºС |
238 |
522* |
Triethylenediamine |
6,9 |
- |
Does not smolder, sublimes |
106 |
317* |
Urotropin |
15,1 |
683 |
- |
- |
- |
Phenolic resin |
25 |
460 |
Does not smolder, melts at 80-90 ºС |
- |
- |
Phenoplast |
36,8 |
491 |
227 |
- |
485 |
Ferrocene, bis (cyclopentadienyl) - iron |
9,2 |
487 |
Does not smolder |
120 |
250 |
Phthalic anhydride |
12,6 |
605 |
Does not smolder, melts at 130 ºС |
- |
- |
Cyclopentadienyl tricarbonyl-manganese |
4,6 |
275 |
- |
96 |
265 |
Tsikoriy |
40 |
253 |
- |
- |
190 |
Ebonite |
7,6 |
360 |
Does not smolder, sinter |
- |
- |
Epoxy resin E-49, TU 6-05-1420-71 |
17,2 |
477 |
Does not smolder |
330 |
486 |
Epoxy composition EP-49SP, TU 6-05-241-98-75 |
32,8 |
- |
Also |
325 |
450 |
Epoxy composition UP-2196 |
22,3 |
- |
Also |
223 |
358 |
Epoxy dust (waste in the processing of epoxy compounds) |
25,5 |
643 |
198 |
200 |
494 |
Epoxy composition UP-2155, TU 6-05-241-26-72 |
29,5 |
596 |
Does not smolder |
311 |
515 |
Epoxy composition UP-2111, TU 6-05-241-11-71 |
23,5 |
654 |
Also |
310 |
465 |
2-Ethylanthraquinone |
15,8 |
- |
Does not smolder, melts at 107 ºС |
207 |
574* |
Ethylsilsexvioxane (P1E) |
64,1 |
707 |
223 |
223 |
420 |
Ethylcellulose |
37,8 |
657 |
Does not smolder, decomposes at 240 ºС |
- |
- |
Tea |
32,8 |
925 |
220 |
- |
* Self-ignition temperature of the molten substance.
See other articles Section Rules for the installation of electrical installations (PUE).
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