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ENCYCLOPEDIA OF RADIO ELECTRONICS AND ELECTRICAL ENGINEERING
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Section 7. Electrical equipment of special installations

Electrical installations in hazardous areas. Classification of explosive mixtures according to GOST 12.1.011-78

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Encyclopedia of radio electronics and electrical engineering / Rules for the installation of electrical installations (PUE)

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7.3.26. Explosive mixtures of gases and vapors with air, depending on the size of the BEMZ, are divided into categories according to Table. 7.3.1.

7.3.27. Explosive mixtures of gases and vapors with air, depending on the temperature of self-ignition, are divided into six groups according to Table. 7.3.2.

7.3.28. The distribution of explosive mixtures of gases and vapors with air by categories and groups is given in Table. 7.3.3.

Table 7.3.1. Categories of explosive mixtures of gases and vapors with air *

Blend category Mixture name BEMZ, mm
I mine methane More 1,0
II Industrial gases and vapors -
IIA Also More 0,9
IIB Also More than 0,5 to 0,9
IIC Also Until 0,5

* The BEMZ values ​​given in the table cannot be used to control the shell gap width in operation.

Table 7.3.2. Groups of explosive mixtures of gases and vapors with air by auto-ignition temperature

Group Self-ignition temperature of the mixture, ºС Group Self-ignition temperature of the mixture, ºС
T1 above 450 T4 Above 135 to 200
T2 "300 to 450 T5 "100 to 135
TK "200 to 300 T6 "85 to 100

Table 7.3.3. Distribution of explosive mixtures by categories and groups

Blend category Mix group Substances that form an explosive mixture with air
I T1 Methane (mine)*
iia T1 Ammonia, allyl chloride, acetone, acetonitrile, benzene, benzotrifluoride, vinyl chloride, vinylidene chloride, 1,2-dichloropropane, dichloroethane, diethylamine, diisopropyl ether, blast furnace gas, isobutylene, isobutane, isopropylbenzene, acetic acid, xylene, methane (industrial)**, methyl acetate, α-methylstyrene, methyl chloride, methyl isocyanate, methyl chloroformate, methylcyclopropyl ketone, methyl ethyl ketone, carbon monoxide, propane, pyridine, solvents R-4, R-5 and RS-1, diluent RE-1, petroleum solvent, styrene, diacetone alcohol, toluene, trifluorochloropropane, trifluoropropene, trifluoroethane, trifluorochlorethylene, triethylamine, chlorobenzene, cyclopentadiene, ethane, ethyl chloride
T2 Alkylbenzene, amyl acetate, acetic anhydride, acetylacetone, acetyl chloride, acetopropyl chloride, gasoline B95/130, butane, butyl acetate, butyl propionate, vinyl acetate, vinylidene fluoride, diatol, diisopropylamine, dimethylamine, dimethylformamide, isopentane, isoprene, isopropylamine, isooctane, propionic acid, methylamine , methylisobutyl ketone, methyl methacrylate, methyl mercaptan, methyltrichlorosilane, 2-methylthiophene, methylfuran, monoisobutylamine, methylchloromethyldichlorosilane, mesityl oxide, pentadiene-1,3, propylamine, propylene. Solvents: No. 646, 647, 648, 649, RS-2, BEF and AE. Thinners: RDV, RKB-1, RKB-2. Alcohols: butyl normal, butyl tertiary, isoamyl, isobutyl, isopropyl, methyl, ethyl. Trifluoropropylmethyldichlorosilane, trifluoroethylene, trichlorethylene, isobutyl chloride, ethylamine, ethyl acetate, ethylbutyrate, ethylenediamine, ethylenechlorohydrin, ethylisobutyrate, ethylbenzene, cyclohexanol, cyclohexanone
IIA T3 Gasolines: A-66, A-72, A-76, “galosh”, B-70, extraction according to TU 38.101.303-72, extraction according to MRTU12N-20-63. Butyl methacrylate, hexane, heptane, diisobutylamine, dipropylamine, isovaleric aldehyde, isooctylene, camphene, kerosene, morpholine, petroleum, petroleum ether, TGM-3 polyester, pentane, solvent No. 651, turpentine, amyl alcohol, trimethylamine, T-1 and TS fuel -1, white spirit, cyclohexane, cyclohexylamine, ethyl dichlorothiophosphate, ethyl mercaptan
IIA T4 Acetaldehyde, isobutyric aldehyde, butyric aldehyde, propionic aldehyde, decane, tetramethyldiaminomethane, 1,1,3-triethoxybutane
T5 -
T6 -
IIB T1 coke oven gas, hydrocyanic acid
T2 Divinyl, 4,4-dimethyldioxane, dimethyldichlorosilane, dioxane, diethyldichlorosilane, camphor oil, acrylic acid, methyl acrylate, methylvinyldichlorosilane, acrylic acid nitrile, nitrocyclohexane, propylene oxide, 2-methylbutene-2 ​​oxide, ethylene oxide, AMP-3 and AKP solvents , trimethylchlorosilane, formaldehyde, furan, furfural, epichlorohydrin, ethyltrichlorosilane, ethylene
IIB T3 Acrolein, vinyl trichlorosilane, hydrogen sulfide, tetrahydrofuran, tetraethoxylan, triethoxysilane, diesel fuel, formal glycol, ethyl dichlorosilane, ethyl cellosolve
T4 Dibutyl Ether, Diethyl Ether, Ethylene Glycol Diethyl Ether
T5 -
T6 -
IIC T1 Hydrogen, water gas, light gas, hydrogen 75% + nitrogen 25%
T2 Acetylene, methyldichlorosilane
T3 Trichlorosilane
T4 -
T5 carbon disulfide
T6 -

* Mine methane should be understood as mine gas, in which, in addition to methane, the content of gaseous hydrocarbons - homologues of C2-C5 methane - is no more than 0,1 volume fraction, and hydrogen in gas samples from boreholes immediately after drilling is no more than 0,002 volume fraction of the total volume of combustible gases .

** In industrial methane, the hydrogen content can be up to 0,15 volume fraction.

7.3.29. The lower concentration limit of ignition of some explosive dusts, as well as their smoldering, ignition and self-ignition temperatures are given in Table. 7.3.4.

7.3.30. Categories and groups of explosive mixtures of gases and vapors with air, as well as smoldering, ignition and self-ignition temperatures of dust not included in the table. 7.3.3 and 7.3.4 are determined by testing organizations in accordance with their list in accordance with GOST 12.2.021-76.

Table 7.3.4. The lower concentration limit of ignition, the temperature of smoldering, ignition and self-ignition of explosive dusts

Substance suspended dust Settled dust
Lower concentration limit of ignition, g/m3 Ignition temperature, ºС Smoldering temperature, ºС Ignition temperature, ºС Self-ignition temperature, ºС
adipic acid 35 550 - 320 410
Altax 37,8 645 Does not smolder, melts at 186 ºС - -
Aluminum 40 550 320 - 470
Aminopelargonic acid 10 810 Does not smolder, melts at 190 ºС - -
Aminoplast 52 725 264 - 559
Aminoenanthic acid 12 740 Does not smolder, melts at 195 ºС 390 450*
4-Amilbenzophenone 2-carboxylic acid 23,4 562 Does not smolder, melts at 130 ºС 261 422*
Ammonium salt of 2,4-dioxybenzene-sulfonic acid 63,6 - Does not smolder, melts 286 470
Anthracene 5 505 Does not smolder, melts at 217 ºС - -
Atrazine technical, TU BU-127-69 30,4 779 Does not smolder, melts at 170 ºС 220 490*
Atrazine commercial 39 745 Also 228 487*
Sunflower food protein 26,3 - 193 212 458
soy protein food 39,3 - Does not smolder, charred 324 460
Bis(trifluoroacetate)dibutyltin 21,2 554 Does not smolder, melts at 50 ºС 158 577*
Vitamin B15 28,2 509 - - -
Vitamin PP from rose hips 38 610 - - -
Hydroquinone 7,6 800 - - -
Pea flour 25 560 - - -
Dextrin 37,8 400 - - -
Dicyclopentadiene dioxide, TU 6-05-241-49-73 19 - Does not smolder 129 394
2,5-Dimethylhexin-3-diol-2,5 9,7 - Does not smolder, melts at 90ºС 121 386*
wood flour 11,2 430 - - 255
casein 45 520 - - -
Cocoa 45 420 245 - -
Camphor 10,1 850 - - -
Rosin 12,6 325 Does not smolder, melts at 80ºС - -
Kerogen 25 597 - - -
Potato starch 40,3 430 Does not smolder, charred - -
Corn starch 32,5 410 Does not smolder, charred - -
hardwood lignin 30,2 775 - - 300
Cotton lignin 63 775 - - -
Softwood lignin 35 775 - - 300
Dibutyltin maleate 23 649 - 220 458*
Maleic anhydride 50 500 Does not smolder, melts at 53º C - -
Methyltetrahydrophthalic anhydride 16,3 488 Does not smolder, melts at 64ºС 155 482*
Microvit A feed, TU 64-5-116-74 16,1 - Does not smolder, charred 275 463
Flour dust (wheat, rye and other grain crops) 20-63 410 - - 205
Naphthalene 2,5 575 Does not smolder, melts at 80ºС - -
Dibutyltin oxide 22,4 752 154 154 523
Dioctyltin oxide 22,1 454 Does not smolder, melts at 155 ºС 155 448*
Polyacrylonitrile 21,2 505 Does not smolder, charred 217 -
Polyvinyl alcohol 42,8 450 Does not smolder, melts at 180-220 ºС 205 344*
Polyisobutylaluminumoxane 34,5 - Does not smolder 76 514
Polypropylene 12,6 890 - - -
Polysebacin anhydride (hardener VII-607), MRTU 6-09-6102-69 19,7 538 Does not smolder, melts at 80 ºС 266 381*
Polystyrene 25 475 Does not smolder, melts at 220ºС - -
Powder paint P-EP-177, item 518 VTU 3609-70, with additive No. 1, gray color 16,9 560 Does not smolder 308 475
Powder paint P-EP-967, item 884, VTU 3606-70, red-brown color 37,1 848 Also 308 538
Powder paint EP-49-D/2, VTU 605-1420-71, brown 33,6 782 Also 318 508
Powder paint PVL-212, MPTU 6-10-859-69, ivory 25,5 580 - 241 325
Powder paint P-EP-1130U, VTU NC No. 6-37-72 33,5 633 Also 314 395
Propazine technical 27,8 775 Does not smolder, melts at 200 ºС 226 435*
Commercial propazine, TU 6-01-171-67 37,2 763 Does not smolder, melts at 200 ºС 215 508*
cork flour 15 460 325 - -
Dust of Leninsk-Kuznetsk hard coal grade D, Yaroslavsky mine 31 720 149 159 480
Industrial rubber dust 10,1 1000 - - 200
Dust industrial cellolignin 27,7 770 - - 350
Shale dust 58 830 - 225
Sucap (acrylic acid polymer TU 6-02-2-406-75) 47,7 - Does not smolder 292 448
Beet sugar 8,9 360 Does not smolder, melts at 160 ºС - 350*
Sulfur 2,3 235 Does not smolder, melts at 119 ºС - -
Simazin technical, TU BU-104-68 38,2 790 Does not smolder, melts at 220 ºС 224 472*
Simazin commodity, MRTU 6-01-419-69 42,9 740 Does not smolder, melts at 225 ºС 265 476*
Resin 113-61 (dioctyltin thioestanate) 12 - Does not smolder, melts at 68 ºС 261 389*
Salt AG 12,6 636 - - -
Copolymer of acrylonitrile with methyl methacrylate 18,8 532 Does not smolder, charred 274 -
Stabilizer 212-05 11,1 - Does not smolder, melts at 57 ºС 207 362*
Glass organic 12,6 579 Does not smolder, melts at 125 ºС - 300*
Sulfadimezin 25 900 - - -
Titanium 45 330 - - -
Thiooxyethylene dibutyltin 13 214 Does not smolder, melts at 90 ºС 200 228*
Triphenyltrimethylcyclotrisiloxane 23,4 515 Does not smolder, melts at 60 ºС 238 522*
Triethylenediamine 6,9 - Does not smolder, sublimes 106 317*
Urotropin 15,1 683 - - -
Phenolic resin 25 460 Does not smolder, melts at 80-90 ºС - -
Phenoplast 36,8 491 227 - 485
Ferrocene, bis (cyclopentadienyl) - iron 9,2 487 Does not smolder 120 250
Phthalic anhydride 12,6 605 Does not smolder, melts at 130 ºС - -
Cyclopentadienyl tricarbonyl-manganese 4,6 275 - 96 265
Tsikoriy 40 253 - - 190
Ebonite 7,6 360 Does not smolder, sinter - -
Epoxy resin E-49, TU 6-05-1420-71 17,2 477 Does not smolder 330 486
Epoxy composition EP-49SP, TU 6-05-241-98-75 32,8 - Also 325 450
Epoxy composition UP-2196 22,3 - Also 223 358
Epoxy dust (waste in the processing of epoxy compounds) 25,5 643 198 200 494
Epoxy composition UP-2155, TU 6-05-241-26-72 29,5 596 Does not smolder 311 515
Epoxy composition UP-2111, TU 6-05-241-11-71 23,5 654 Also 310 465
2-Ethylanthraquinone 15,8 - Does not smolder, melts at 107 ºС 207 574*
Ethylsilsexvioxane (P1E) 64,1 707 223 223 420
Ethylcellulose 37,8 657 Does not smolder, decomposes at 240 ºС - -
Tea 32,8 925 220 -

* Self-ignition temperature of the molten substance.

See other articles Section Rules for the installation of electrical installations (PUE).

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