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Atmospheric emissions of the city-millionaire. Basics of safe life
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The composition of industrial and domestic emissions of the millionaire city entering the atmosphere is very diverse.
Annual amount of gaseous emissions and their composition are given below (in thousand tons/year):
Water (steam, aerosol) |
10800 |
Carbon dioxide |
1200 |
Sulfur dioxide |
240 |
Carbon monoxide |
240 |
Dust |
180 |
Hydrocarbons |
108 |
Nitrogen oxides |
60 |
Organic substances (phenols, benzene, alcohols, solvents, fatty acids) |
8 |
Chlorine, hydrochloric acid aerosols |
5 |
Hydrogen sulfide |
5 |
Ammonia |
1,4 |
Fluorides, in terms of fluorine |
1,2 |
carbon disulfide |
1,0 |
Hydrogen cyanide |
0,3 |
Lead compounds |
0,5 |
Nickel (as part of dust) |
0,042 |
PAHs (including benzapyrene) |
0,08 |
arsenic |
0,031 |
Uranium (as part of dust) |
0,024 |
Cobalt (as part of dust) |
0,018 |
Mercury |
0,0084 |
Cadmium (as part of dust) |
0,0015 |
Beryllium (as part of dust) |
0,0012 |
The largest share in the composition of atmospheric emissions belongs to water (water vapor and aerosols) and carbon dioxide, followed by sulfur dioxide, carbon monoxide and dust. The density of emissions of these substances per year from 1 km of the area of a millionaire city (in the model, its average area is 300 km2) for sulfur dioxide and carbon monoxide is about 240 tons, dust is about 180 tons, and nitrogen oxides is about 60 tons. It should be emphasized that the intra-annual distribution of these emissions is quite uneven. The maximum emissions into the atmosphere are observed in the winter months, when thermal power plants and boiler houses operate at full capacity.
Another important component of pollution in the lower layer of the atmosphere is hydrocarbons, which are emitted annually up to 108 thousand tons.
The next considered group of substances entering the air of cities is contained in quantities 1-2 orders of magnitude less than the previous ones. This includes organic substances, the total mass of which reaches 8 thousand tons / year (phenols, alcohols, solvents, fatty acids, benzene). Hydrogen sulfide and chlorine in combination with hydrochloric acid aerosols are emitted into the atmosphere in approximately equal amounts - 5 thousand tons each. About 1 tons of carbon disulfide enters the air every year, and a little more - fluorides and ammonia.
The amount of emissions from the group of substances most toxic to humans and wildlife - lead, mercury, arsenic, cadmium, benzapyrene - is up to several tons per year.
Emissions of pollutants into the atmosphere leave their mark on the earth. This is being monitored systematically. The background pollution of the snow cover and the pollution of the snow cover around the cities are investigated. Data on pollutant emission zones around cities and surrounding territories are of great interest, as they clearly demonstrate the impact of cities on these territories, including agricultural land, recreation areas, water bodies, protected landscapes, etc. Research is carried out using artificial satellites Earth.
Table 2. Correlation between the areas of cities and pollutant haloes around them
City population, thousand people |
Average urban area, km2 |
Average area of pollution halo, km2 |
Distance of the edge of the pollution halo from the city center, km |
the greatest |
the smallest |
More than 1 |
179 |
3390 |
59 |
13 |
999-500 |
74 |
2370 |
44 |
12 |
499-100 |
34 |
1550 |
33 |
10 |
99-50 |
22 |
385 |
26 |
2 |
Table 2 shows the average values of built-up areas and pollution zones around them, as well as the distance of the edges of these zones from city centers. The data was obtained based on the analysis of materials for 540 cities of Russia.
National averages, of course, differ significantly from city-specific figures. Thus, individual pollution halos around Moscow, other cities and towns of the Central Economic Region merged into a single spot (with an area of 177,9 thousand km2) - from Tver in the northwest to Nizhny Novgorod in the northeast, from the southern borders of the Kaluga region to the south -west to the borders of Mordovia in the southeast. The pollution zone around Yekaterinburg exceeds 32,5 thousand km2, around the Irkutsk-Cherekhov industrial region - 31 thousand km2.
Authors: Aizman R.I., Krivoshchekov S.G.
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