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ENCYCLOPEDIA OF RADIO ELECTRONICS AND ELECTRICAL ENGINEERING
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On the preparation of ferric chloride. Encyclopedia of radio electronics and electrical engineering

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Encyclopedia of radio electronics and electrical engineering / Ham Radio Technologies

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In "Radio" (1990. No. 8. P. 74) a note by A. Sergienko and V. Ivanenko "Preparation of ferric chloride" was published, which describes how to prepare iron trichloride for etching circuit boards under amateur conditions. The essence of this method is the treatment of ordinary rust with hydrochloric acid. However, gaining the required amount of rust is not as easy as it seems. In addition, it inevitably contains a lot of "dirt" that spoils the final product.

I solved this problem chemically. When ferrous sulfate is calcined on fire (it can be purchased at stores selling household chemicals or garden supplies), water first evaporates from it and a white mass of anhydrous iron sulfate salt remains. With further heating (at a temperature of more than 480 ° C), the mass decomposes with the release of gaseous sulfur oxides, which form sulfuric acid vapors in the air. Therefore, work must be carried out under a good hood or in the open air. In the process of calcination, it is necessary to crush the sintering mass.

After some time, it turns into a fine rust powder of fairly high purity. Store the powder in an airtight container, as it is hygroscopic and because of this it cakes into lumps.

The chemical substantiation of the process of obtaining rust is set out in Glinka's textbook N. L. "General Chemistry" (for example, 1975 on p. 680).

Author: V.Zabironin, Lutsk, Ukraine

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