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ENCYCLOPEDIA OF RADIO ELECTRONICS AND ELECTRICAL ENGINEERING
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Semiconductor materials and products. Encyclopedia of radio electronics and electrical engineering

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Encyclopedia of radio electronics and electrical engineering / Electricity for beginners

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Semiconductors include a large number of materials that differ from each other in internal structure, chemical composition and electrical properties. According to the chemical composition, crystalline semiconductor materials are divided into 4 groups:

1) materials consisting of atoms of one element: germanium, silicon, selenium, phosphorus, boron, indium, gallium, etc.;

2) materials consisting of metal oxides: copper oxide, zinc oxide, cadmium oxide, titanium dioxide, etc.;

3) materials based on compounds of atoms of the third and fifth groups of the Mendeleev's system of elements, denoted by the general formula and called antimonides. This group includes compounds of antimony with indium, with gallium, etc., compounds of atoms of the second and sixth groups, as well as compounds of atoms of the fourth group;

4) semiconductor materials of organic origin, such as polycyclic aromatic compounds: anthracene, naphthalene, etc.

According to the crystal structure, semiconductor materials are divided into 2 groups: single-crystal and polycrystalline semiconductors.

The first group includes materials obtained in the form of large single crystals (single crystals). Among them are germanium, silicon, from which plates are cut for rectifiers and other semiconductor devices.

The second group of materials are semiconductors, which consist of many small crystals soldered together.

Polycrystalline semiconductors are: selenium, silicon carbide, etc.

In terms of volume resistivity, semiconductors occupy an intermediate position between conductors and dielectrics. Some of them dramatically reduce electrical resistance when exposed to high voltage. This phenomenon has found application in valve arresters for the protection of power lines. Other semiconductors dramatically reduce their resistance when exposed to light. This is used in photocells and photoresistors.

A common property for semiconductors is that they have both electron and hole conduction.

Author: Smirnova L.N.

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