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Nanomaterial of molecules twisted simultaneously in opposite directions

21.09.2019

Many biomolecules have such a property as chirality: two molecules with exactly the same structure are mirror images of each other. The most striking example of chirality is our hands: the left mirrors the right and vice versa. Another example that we see in nature is the spiral of a shell, which can be twisted to the right or to the left. "Mirror" molecules with the same structure can have completely different properties. Conventionally, a molecule twisted in one direction smells like lemons, and when it rotates in the other direction, it smells like oranges.

The detection of these distortions is especially important in some industries such as pharmaceuticals, perfumes, food additives and pesticides. Recently, a new class of nanomaterials, plasmonic nanomaterials, has been developed that can help distinguish between the chirality of molecules. These nanomaterials enhance the chiral properties of molecules when exposed to light. They are usually made up of tiny twisted metal "wires" that are themselves chiral. However, the researchers ran into a difficulty: it became very difficult to distinguish between the twist of the nanomaterial itself and the swirl of the molecules whose properties were to be studied.

To solve this problem, a team from the Department of Physics at the University of Bath created a nanomaterial that twists in one direction and the other at the same time. This nanomaterial has the same number of molecules twisted in opposite directions, which means that they cancel each other out. Therefore, when interacting with laser beams, this material remains in its usual state, without showing the properties of chirality.

The team used a mathematical analysis of the material's symmetry properties and found several special cases that could reveal a "hidden" twist and allow detection of chirality in molecules with great precision.

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Global warming asymmetry 07.10.2020

New research shows that stronger nighttime warming is more common worldwide than stronger daytime warming. Scientists at the University of Exeter studied warming from 1983 to 2017 and found a difference in average annual temperature of more than 0,25°C between daytime and nighttime warming over more than half of the land surface.

Days warmed faster in some places and nights warmed faster in others, but the total area of ​​disproportionate warming at night was twice that.

The "warming asymmetry" was mainly due to changes in cloud levels. Increased cloud cover cools the surface during the day and retains heat at night, resulting in even more warming at night.

"Warming asymmetries could have major implications for the natural world," said lead author Dr Daniel Cox of the Institute for Environment and Sustainability at Exeter's Penryn campus in Cornwall.

Stronger nighttime warming is associated with a wetter climate, and this has been shown to have important implications for plant growth and how species such as insects and mammals interact.

Greater diurnal warming is associated with drier conditions coupled with higher levels of overall warming, which increases species vulnerability to heat stress and dehydration.

"Species that are active only at night or during the day will be especially affected," the scientists say.

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