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Efficient Oil Spill Cleanup

14.10.2012

Researchers Mike Chang and Zuepei Yuan point out that the current methods of cleaning up oil slicks, which were used, for example, to clean up the consequences of a deep-sea disaster in 2010, are in fact low-tech, decades outdated and have many disadvantages. The absorbents used, such as corncobs and straw, absorb only five times their weight, not only oil, but also water. After that, they become industrial waste, which require incineration or disposal in special landfills.

The scientists' solution is a polymeric material that converts the stain into a soft, oily gel that is dense enough to be mechanically collected and transported. In addition, the gel is amenable to liquefaction and subsequent purification similar to conventional crude oil. One kilogram of this substance can absorb about 40 liters of crude oil. At the current market price of crude oil of about $100 per barrel, the cost of this collection method would be only about $15.

The publication of the authors describes a new approach that will comprehensively solve the problem of oil slicks. The technology focuses on a cross-linked polyalkene trimer (x-OS-DVB) containing 1-octene, styrene and divinylbenzene, a superabsorbent petroleum polymer with aliphatic and amino acid compounds. The combination of selective oil absorption (i.e. without water) with high mechanical strength ensures buoyancy, reliability and ease of collection from the water surface. The collected oil gel, consisting of 98% oil and 2% x-OS-DVB, is suitable for conventional oil refining processes - economical, waste-free and with a very low percentage of harmful emissions. In addition, polyalkene is one of the cheapest polymers, the production of which is quite simple to set up around the world.

Overall, this new cost-effective technology can significantly reduce the environmental impact of oil slicks.

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Random news from the Archive

Packaging affects the properties of water 28.09.2013

Scientists at the Georgia Institute of Technology have found that the properties of the pipeline material affect the viscosity of water. True, this is noticeable only at the nanolevel.

The phenomenon does not affect the speed at which water pours out of the bottle, but at the nanoscale, under specific conditions, differences in the behavior of water are clearly visible. A new study shows that in nanoscopic glass channels, the viscosity of water can be twice as high as in plastic channels. Simply put, in nanoscale glass channels, water behaves like a ketchup-thick liquid.

At first glance, this discovery is of little use, but in fact it is very important, especially in light of the spread of nanotechnologies, such as microfluidic chips, designed to instantly diagnose infectious diseases. In addition, this information is important for developers of micromechanical systems, ultra-precise 3D printers and other devices where liquids have to be forced through tiny holes.

Changing the viscosity of water is another example of amazing phenomena at the nanoscale. It has long been known that the so-called hydrophilic materials attract water molecules and impede their movement, while hydrophobic materials, on the contrary, make it easier. But at the macro level, this is not so noticeable, but at the nano level, when water moves in a layer of only a few molecules, the viscosity increases sharply due to the fact that water molecules “stick” to the hydrophilic surface and move in a closer group.

The researchers studied the behavior of water at the nanoscale on various types of surfaces: mica, graphene oxide, silicon, diamond-like carbon and graphite. Mica, used in the drilling industry, and at the nanoscale, turned out to be the most hydrophilic material, while graphite was the most hydrophobic.

Scientists believe that a sharp increase in viscosity on hydrophilic surfaces will be observed for other liquids, not just water. Thus, developers of miniature machines, metamaterials, nanostructured materials, etc. this factor should be taken into account.

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