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Green polyethylene

14.03.2009

At a conference on bioplastics held in 2008 in Cologne (Germany), Brazilian chemists talked about their new development: they learned how to make polyethylene from sugar cane.

First, ethyl alcohol is obtained from sugar cane using a routine process, and then the alcohol is converted into ethylene by a dehydration reaction. Finally, ethylene is polymerized in the usual way. By-products are mainly water with a small amount of ether and unreacted alcohol.

"Green" polyethylene is no different from conventional polyethylene, except for small differences in the isotopic composition of carbon (plant carbon is slightly different from oil carbon). So if a company begins to claim that its polyethylene is produced without harming the environment, then this statement can be verified by carbon isotopes.

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High Efficiency Heat Resistant Solar Panel 28.10.2013

Scientists from Stanford University, the University of Illinois-Urbana Champaign and North Carolina State University have created a heat-resistant thermal emitter that can significantly increase the efficiency of solar panels - theoretically up to 80%. The new solar cell component is designed to convert solar heat into infrared radiation, which is absorbed by the solar cell and increases its power.

A conventional solar cell is based on semiconductor silicon, which absorbs the energy of sunlight and converts it into electrical energy. But silicon semiconductors process only infrared light, and other waves, including most of the visible spectrum, are wasted: they are dissipated as heat. Therefore, in theory, conventional silicon panels can achieve an efficiency of about 34%, but in practice they do not reach even this, because they simply reflect and dissipate the energy of sunlight.

The new thermophotovoltaic panel solves this problem. Instead of transmitting sunlight directly to a solar cell, a thermophotovoltaic cell has an intermediate component that consists of two parts: an absorber (heats up when exposed to sunlight) and an emitter (converts heat into infrared radiation). Simply put, the new cell "recodes" sunlight into shorter wavelengths that are ideal for absorption by the solar cell. This makes it possible to increase the theoretical efficiency of the cell up to 80%.

Unfortunately, the thermophotovoltaic solar panel prototype has so far been nowhere near this efficiency: in the laboratory, it shows an efficiency of about 8%. The low performance is largely due to the insufficient thermal stability of the heat converter. The emitter is a complex, three-dimensional tungsten nanostructure that must operate at temperatures above 1000 degrees Celsius. However, in previous experiments at a given temperature, the emitter was destroyed.

To solve this problem, the scientists coated the emitter with a nanolayer of tungsten and a ceramic material - hafnium dioxide. Unlike previous prototypes, which were completely destroyed at temperatures below 1200 degrees Celsius, the new thermal emitter remains stable at temperatures up to 1 degrees Celsius for at least 1400 hour.

The new thermal emitter is ideal for creating high-efficiency solar panels capable of converting a significant portion of the absorbed sunlight into electricity. At the same time, hafnium and tungsten can be produced in quantities sufficient for the mass production of new solar panels, with an efficiency at least 2 times higher than that of modern commercial solar panels.

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